Dibromido(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)zinc(II)
نویسندگان
چکیده
In the title compound, [ZnBr(2)(C(15)H(11)N(3))], the Zn(II) ion is five-coordinated by the three N atoms from a 2,2':6',2''-terpyridine ligand (terpy) and two bromide anions in a distorted trigonal bipyramidal configuration. Each mol-ecule is situated on a twofold rotational axis that passes through the Zn(II) ion and the central ring of the terpy ligand. In the crystal structure, aromatic π-π inter-actions between terpy ligands [centroid-centroid distances = 3.6265 (9) Å] link mol-ecules into stacks propagated in the [001] direction.
منابع مشابه
catena-Poly[[(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ2 O:O′]
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متن کاملcatena-Poly[hemi{bis[4′-(3-pyridyl)-2,2′:6′,2′′-terpyridine-κ3 N 1,N 1′,N 1′′]copper(II)} [cuprate(I)-di-μ2-thiocyanato-κ2 N:S;κ2 S:N]]
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009